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The study of the mass spectrometric fragmentation of heavy metal-biothiol conjugates has been instrumental in highlighting the key feature of thiol-bound mercury in its conjugates and is again the key to propose a more general mechanism for thiophilic glutathione-bound cations
Also, renewed interest was aroused when it was discovered that GLP-1, unlike all the other insulinotropic peptides from the gut (including GIP but interestingly not including secretin) also was a potent inhibitor of glucagon secretion (62)
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