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doi:10.1016/S0140-6736(19)31149-3 29

Our S-Acetyl L-Glutathione Story We spotted a fundamental challenge with glutathione supplementation: despite being one of the body's most critical protective compounds, standard reduced glutathione has limited bioavailability and requires high doses (500-1,000mg) taken over weeks to see meaningful increases in tissue levels

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The defining structural feature is a side-chaintoside-chain lactam bridge formed between the -carboxyl of Asp(2) and the -amine of Lys(7), producing a homodetic isopeptide macrocycle