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Many hydrolyzed collagen supplements in the market are extracted from chicken sternum cartilage for this reason

It is established copper-ascorbate redox chemistry

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The post says temperatures above the refrigerated range accelerate protein breakdown, while freezing can cause crystallization and a permanent loss of function

Unopened vials remain stable at controlled room temperature (2025C), but once the sterile seal is broken, benzyl alcohol's preservative capacity depends entirely on cold storage to prevent bacterial colonization and maintain pH stability